TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination of 2,3-allenyl perfluoroalkyl ketones.
نویسندگان
چکیده
A unique TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination reaction of easily available n-perfluoroalkyl allenones in the presence of H2O providing furanyl perfluoroalkyl ketones has been developed. The (18)O-labelling experiments confirmed that the oxygen atom of the carbonyl group in the final products originates from water.
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عنوان ژورنال:
- Chemical communications
دوره 51 96 شماره
صفحات -
تاریخ انتشار 2015